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Updated: May 1, 2026

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
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Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions

Published on: October 5, 2019

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固定されたTAMLアクティベーターによる電気触媒酸素進化.

Ethan L Demeter1, Shayna L Hilburg, Newell R Washburn

  • 1Departments of †Chemical Engineering, ‡Materials Science and Engineering, and §Chemistry, Carnegie Mellon University , 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213, United States.

Journal of the American Chemical Society
|April 9, 2014
PubMed
まとめ

炭素基にテトラアミドマクロサイクリック (TAML) アクティベーターを固定することで,水酸化 (WO) の性能が向上します. この新しい異質な電気触媒は,以前の均質なシステムよりも大幅に高いターンオーバー数 (TONs) を達成します.

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Anaerobic Protein Purification and Kinetic Analysis via Oxygen Electrode for Studying DesB Dioxygenase Activity and Inhibition08:31

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Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
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