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Probing C84-embedded Si Substrate Using Scanning Probe Microscopy and Molecular Dynamics
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C-C と C-Si σ-結合の割れ方とその分子内交換

Naoki Ishida1, Wataru Ikemoto, Masahiro Murakami

  • 1Department of Synthetic Chemistry and Biological Chemistry, Kyoto University , Katsura, Kyoto 615-8510, Japan.

Journal of the American Chemical Society
|April 12, 2014
PubMed
まとめ

パラジアム ((0) 触媒は,サイクロブタノンおよびシラサイクロブタンの化合物における炭素-炭素および炭素-シリコン結合を裂き,結合交換を可能にします. この反応により,高度なダイアステロ選択性を持つ複雑なシラビサイクロ[5.2.1]デカンが形成されます.

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