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Updated: May 1, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
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Controlling the Size, Shape and Stability of Supramolecular Polymers in Water

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遠距離クーロンビックとCH··O相互作用によるクキュルビチューリル/ゲスト組の安定化

Roymon Joseph1, Anna Nkrumah, Ronald J Clark

  • 1Department of Chemistry and Biochemistry, Ohio University , Athens, Ohio 45701, United States.

Journal of the American Chemical Society
|April 18, 2014
PubMed
まとめ

Cucurbit[n]urils (CB[n]) は,好ましいエンタルピーによって誘発されるCH··O結合を通じて,金属-テルピリジン複合体を強く結合する. CB[8]は,自己分類とダイナミックで交替する金属オリゴマーの形成を可能にするリンクとして作用する.

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This lesson discusses the stability of substituted cyclohexanes with a focus on energies of various conformers and the effect of 1,3-diaxial interactions.
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