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Updated: Apr 30, 2026

Solid-phase Synthesis of [4.4] Spirocyclic Oximes
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遠隔エステル群が選択性を切り替える:テトラサイクルのスピロインドリンのダイアステロダイバーゲント合成

Jun Zhu1, Yong Liang, Lijia Wang

  • 1State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.

Journal of the American Chemical Society
|April 29, 2014
PubMed
まとめ

クォーターナリーステレオセンターで複雑な分子を合成することは困難です. この研究では,銅で触媒化された反応を導入して,四環スパイロインドリンを作り,エステル群と計算分析を通じてステレオ化学を制御します.

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