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Updated: Apr 29, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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二次ベンジルエーテルによるエナチオ固有の分子内ヘック反応

Michael R Harris1, Mikhail O Konev, Elizabeth R Jarvo

  • 1Department of Chemistry, University of California , Irvine, California 92697-2025, United States.

Journal of the American Chemical Society
|May 24, 2014
PubMed
まとめ

ニッケル触媒によるヘック・サイクライゼーションは,二次ベンジルエーテルからステレオ特異的にエナチオンの濃縮メチレン・サイクロペンタンを生成する. この方法は,複雑な分子のための構成とアルケンの幾何学を制御し,高収量とエナチオ選択性を達成します.

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