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Updated: Apr 29, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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[Re(CO) ](+) と[Mn(CO) ](+) 複合体によるCOのCH3OHへの還元に関する熱化学的洞察

Eric S Wiedner1, Aaron M Appel

  • 1Physical Sciences Division, Pacific Northwest National Laboratory , P.O. Box 999, K2-57, Richland, Washington 99352, United States.

Journal of the American Chemical Society
|May 24, 2014
PubMed
まとめ

一酸化炭素 (CO) をメタノール (CH3OH) に還元するための熱力学的障壁を理解することは極めて重要です. この研究では, [CpRe(PPh3) ((NO) ((CO) ((+) へのH2添加が主な障害であり,リガンドと金属の変異によって最適化される可能性があります.

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