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マネティズム操作: Ru25+のパドルホイールは,軸間相互作用がない

Gina M Chiarella1, F Albert Cotton, Carlos A Murillo

  • 1Department of Chemistry, Texas A&M University , P.O. Box 30012, College Station, Texas 77842-3012, United States.

Journal of the American Chemical Society
|June 1, 2014
PubMed
まとめ

軸リガンドはダイルテニウム電子構造に大きく影響し,塩素とRu2単位間のπ相互作用を可能にします. 非ペアリングされた電子は金属ベースの分子軌道に存在し,磁気およびEPRデータによって確認されています.

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