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Updated: Apr 28, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

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Al (I) センターに σ 結合の酸化添加をします

Terry Chu1, Ilia Korobkov, Georgii I Nikonov

  • 1Department of Chemistry, Brock University , 500 Glenridge Avenue, St. Catharines, Ontario L2S 3A1, Canada.

Journal of the American Chemical Society
|June 4, 2014
PubMed
まとめ

研究者らは,Al ((I)) 化合物を様々なシグマ結合で反応させることで,新しいアルミニウム水素化合物を合成した. この画期的な発見により,最初のアルミニウムボリル水素および新しいシリルおよびフォスフィド水素化合物の生成が可能になった.

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