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Updated: Apr 28, 2026

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
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Published on: September 8, 2013

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平方平面 d8 イリジウム複合体に C-H 結合の酸触媒による酸化添加

Jason D Hackenberg1, Sabuj Kundu, Thomas J Emge

  • 1Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey , New Brunswick, New Jersey 08903, United States.

Journal of the American Chemical Society
|June 5, 2014
PubMed
まとめ

ブロンステッド酸は4座標のイリジウム複合体へのアルキニルC-H結合添加を触媒化し,トランス-C-H添加製品を生成する. 正方形平面カルボニル複合体におけるこの前例のない反応は,C-H活性化化学の新たな道を開く.

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