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Updated: Apr 28, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Rh (III) -触媒化C-H結合機能化によるα-分岐アミンの非対称合成

Apiwat Wangweerawong1, Robert G Bergman, Jonathan A Ellman

  • 1Department of Chemistry, Yale University , New Haven, Connecticut 06520, United States.

Journal of the American Chemical Society
|June 6, 2014
PubMed
まとめ

この研究は,非酸性C−H結合を用いたイミンへの非対称的な分子間添加の最初の方法を紹介しています. 新型のN-perfluorobutanesulfinyl imine置換剤は,高反応性およびダイアステロ選択性を可能にし,エナティオメリックに濃縮されたアミンを生成します.

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