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Determination of the Photoisomerization Quantum Yield of a Hydrazone Photoswitch
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光化学的ヘテロリシスに対する逆転基板の好みは,形交差点制御から生じる

Alexander T Buck1, Christie L Beck, Arthur H Winter

  • 1Department of Chemistry, Iowa State University , 2101d Hach Hall, Ames, Iowa 50011, United States.

Journal of the American Chemical Society
|June 10, 2014
PubMed
まとめ

研究者は,分子構造が興奮状態の化学反応にどのように影響するか調べました. 彼らは,不安定なカルボケーションが光化学反応を好み,安定したカルボケーションが形交差点制御により熱反応を好むことを発見した.

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