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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

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アニオニックアルミナベンゼンで,アロマティックとアンビフィリックの貢献を伴う

Taichi Nakamura1, Katsunori Suzuki, Makoto Yamashita

  • 1Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University , 1-13-27 Kasuga, Bunkyo-ku, 112-8551 Tokyo, Japan.

Journal of the American Chemical Society
|June 17, 2014
PubMed
まとめ

研究者らはアニオンのアルミナベンゼンを合成し,アルミニウムを含む最初のヘテロベンゼンとなった. この芳香化合物は,平面環と,塩基と電ophilesとの反応を可能にするユニークな電子特性を特徴付けています.

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