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Updated: Apr 28, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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sp3 C-H 結合の直接的,触媒的モノフッ素化:イオン選択性の根基ベースのメカニズム

Cody Ross Pitts1, Steven Bloom, Ryan Woltornist

  • 1Department of Chemistry, Johns Hopkins University , 3400 North Charles Street, Baltimore, Maryland 21218, United States.

Journal of the American Chemical Society
|June 20, 2014
PubMed
まとめ

銅 ((I) とセレクトフローアは,銅がプロセスを開始し,驚くべきラジカルチェーンメカニズムを通じて軽度のC-Hフローリネーションを可能にします. この研究は,メカニズムを詳細に説明し,モノフッ素化への好みを説明します.

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