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Updated: Apr 27, 2026

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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Pd触媒によるアーレンのエアロビック酸化結合: 2つのPd (II) - アリル中間体間のトランスメタレーションの証拠

Dian Wang1, Yusuke Izawa, Shannon S Stahl

  • 1Department of Chemistry, University of Wisconsin-Madison , 1101 University Avenue, Madison, Wisconsin 53706, United States.

Journal of the American Chemical Society
|June 27, 2014
PubMed
まとめ

この研究は,アレーンのパラジアム触媒による有酸素酸化結合がバイアリルを形成するために,バイメタリック経路を経由して進行することを明らかにしています. このメカニズムは,2つのパラジウム (II) - アリル中間体間の伝達を含み,運動的および同位体証拠によって支持されています.

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