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ルイス酸が促進したチタンアルキリデンの形成:オレフィントリメリゼーション触媒に関連するオフサイクル中間物質

Aaron Sattler1, David G VanderVelde, Jay A Labinger

  • 1Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology , Pasadena, California 91125, United States.

Journal of the American Chemical Society
|July 10, 2014
PubMed
まとめ

エチレンとα-オレフィンのトリメリゼーションのために2つの新しいフェノキシイミンチタニウム前触媒が合成されました. 1つの前触媒は効率的に1-ヘクセンとC15オレフィンを生成し,もう1つは複雑な反応性を示すが,それでもオレフィントリメリゼーションを可能にします.

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