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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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根二元安定化における機械的結合とトポロジック効果

Marco Frasconi1, Takashi Kikuchi, Dennis Cao

  • 1Department of Chemistry, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208, United States.

Journal of the American Chemical Society
|July 11, 2014
PubMed
まとめ

トポロジーは,メカニカルに相互接続された分子におけるテトラチアフルワレン (TTF) 激素ダイマーのリドックス特性と安定性に大きく影響します. この研究は,単なる結合ではなく,構造的な配置が,ダイマー形成と行動を決定する方法を明らかにしています.

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