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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

Published on: January 17, 2020

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キラル・サイクロプロペニミネスによるエナンチオセレクティブ・ブロンステッド塩基触媒の移行状態分析

Jeffrey S Bandar1, Gregory S Sauer, William D Wulff

  • 1Department of Chemistry, Columbia University , 3000 Broadway, New York, New York 10027, United States.

Journal of the American Chemical Society
|July 17, 2014
PubMed
まとめ

研究者らは,炭素-13の運動同位体効果を用いて,触媒化されたマイケルの加法反応を研究した. 彼らは,炭素-炭素結合の形成が速度を制限するステップであることを発見し,触媒設計に関する重要な洞察を明らかにしました.

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