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Updated: Apr 26, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Published on: November 21, 2017

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L-ラクチドと ε-カプロラクトンに対するグループ4の金属環開きポリメリゼーション活性に対するレドックス制御

Xinke Wang1, Arnaud Thevenon, Jonathan L Brosmer

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles , 607 Charles E. Young Drive East, Los Angeles, California 90095, United States.

Journal of the American Chemical Society
|July 26, 2014
PubMed
まとめ

フェロセネリガンドを用いた金属複合体のレドックス制御は,ラクチドとカプロラクトンのポリメリゼーション率を調節した. このスイッチング行動は,単一の反応容器でブロックコポリマーの合成を可能にしました.

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