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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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1,4-ディアゼピン合成のための多成分 [5 + 2] サイクル添加反応: アゾメチンイリドの分離と反応性

Dong Jin Lee1, Hong Sik Han, Jinhwan Shin

  • 1Department of Chemistry, Kangwon National University , 1 Kangwondaehak-gil, Chuncheon 200-701, Korea.

Journal of the American Chemical Society
|August 8, 2014
PubMed
まとめ

研究者らは,ロジウム触媒反応を用いて,空気に安定したアゾメチンイリドを開発した. この方法により,最初の触媒的多成分 [5 + 2] サイクル添加が可能になり,生物学的に活性な1,4-ディアゼピン化合物が得られます.

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