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Updated: Apr 24, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
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光化学的ATRPでは,どのようにラジカルが (再生) されるのでしょうか?

Thomas G Ribelli1, Dominik Konkolewicz, Stefan Bernhard

  • 1Department of Chemistry, Carnegie Mellon University , 4400 Fifth Ave, Pittsburgh, Pennsylvania 15213, United States.

Journal of the American Chemical Society
|September 2, 2014
PubMed
まとめ

光化学的に媒介された銅基原子移転ラジカルポリメリゼーション (ATRP) は,主にアミンによる銅複合体の光化学的還元に依存しています. このメカニズムは,電子移転 (ARGET) ATRPによって再生された光化学アクティベータに似ており,急性再生を支配しています.

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