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Facile Preparation of 4-Substituted Quinazoline Derivatives
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キノンのヒドリド抽出のメカニズム

Xingwei Guo1, Hendrik Zipse, Herbert Mayr

  • 1Department Chemie, Ludwig-Maximilians-Universität München , Butenandtstraße 5-13 (Haus F), 81377 München, Germany.

Journal of the American Chemical Society
|September 9, 2014
PubMed
まとめ

この研究では,C-H,Sn-H,B-Hドナーから2,3-ジクロロ-5,6-ディシアノ-p-ベンゾキノン (DDQ) によるヒドリド抽出のための明確な反応機構を明らかにしています. 量子化学と同位体研究は,これらの異なる経路を支持し,極性有機反応の予測に影響を与えます.

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