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Updated: Apr 24, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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イソトープ効果,ダイナミックマッチング,ウィティッグ反応における溶媒のダイナミクス. ベタインはバイパスされた中間物質として用いられる

Zhuo Chen1, Yexenia Nieves-Quinones, Jack R Waas

  • 1Department of Chemistry, Texas A&M University , P.O. Box 30012, College Station, Texas 77842, United States.

Journal of the American Chemical Society
|September 12, 2014
PubMed
まとめ

この研究では,同位体効果と計算方法を使用してウィティグ反応機構を調査しています. 結果は,溶媒のダイナミクスの影響を受け,一時的な中間物質によるサイクル添加経路を示唆しています.

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