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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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アミノアルカノ酸とエステルのデカルボキシラティブアリレーションは,二重触媒作用によるものです

Simon B Lang1, Kathryn M O'Nele, Jon A Tunge

  • 1Department of Chemistry, The University of Kansas , 2010 Malott Hall, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045, United States.

Journal of the American Chemical Society
|September 18, 2014
PubMed
まとめ

この研究では,室温でのフォトレドックスとパラジウム触媒を用いたアリレーションのための新しい方法が紹介されています. このプロセスはエステルからアルケンを効率的に生成し,副産物として二酸化炭素のみを生成します.

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