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Updated: Apr 23, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
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Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

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非常に反応性の高いベンジヒドリルカチオンは,水氷で分離され安定した

Paolo Costa1, Miguel Fernandez-Oliva, Elsa Sanchez-Garcia

  • 1Lehrstuhl für Organische Chemie II, Ruhr-Universität Bochum , 44780 Bochum, Germany.

Journal of the American Chemical Society
|September 20, 2014
PubMed
まとめ

ディフェニルカルベン (DPC) は,水素と水との結合によってトリプルからシングレット基底状態に切り替わります. 低温では,DPCは水に挿入したり,無形氷の中で安定したベンジヒドリルカチオンを形成します.

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