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Updated: Apr 23, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
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触媒的に非対称なα-イミノール再配置:新しいキラルプラットフォーム

Xin Zhang1, Richard J Staples, Arnold L Rheingold

  • 1Department of Chemistry, Michigan State University , East Lansing, Michigan 48824, United States.

Journal of the American Chemical Society
|September 24, 2014
PubMed
まとめ

研究者らは,α-ヒドロキシイミンをα-アミノケトンに変換する新種のジルコニウムベースのキラル触媒を発見した. この高度なエナチオセレクティブ性の高い触媒は,様々な基板に対して優れた収量とエナチオメール過剰 (ee) を達成します.

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