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Updated: Apr 23, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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裸のアリルアニオンの水素化における選択性と同位体効果

Charles L Perrin1, Gabriel J Reyes-Rodríguez

  • 1Department of Chemistry & Biochemistry, University of California-San Diego , La Jolla, California 92093-0358, United States.

Journal of the American Chemical Society
|October 4, 2014
PubMed
まとめ

研究者は,溶液中の裸のアリルアニオンの反応性を,その水酸化を研究することによって特徴づけました. 競争実験では,低選択性が示され,高塩基性を示し,その振る舞いをアリルチウムまたはアリルグリナード反応剤と対比した.

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