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Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
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Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction

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リメチル複合体の選択的電気触媒酸化により,表面に結合したRu (II) ポリピリジル触媒によってメタノールに変換される

Michael K Coggins1, Manuel A Méndez, Javier J Concepcion

  • 1Department of Chemistry, University of North Carolina at Chapel Hill , Chapel Hill, North Carolina 27599, United States.

Journal of the American Chemical Society
|October 18, 2014
PubMed
まとめ

本研究では,選択的メチルルヘニウム三酸化物 (MTO) をメタノールに酸化するためのナノITO電極上のルテニウム触媒 (Ru) を提示しています. 触媒は,提案されたレニウム-メチル結合挿入メカニズムを通じて,高いメタノール収量を達成します.

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