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Updated: Apr 21, 2026

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
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Published on: September 8, 2013

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シリロンの電子誘発による変換により,六基の周期性シリレンに変換される

Sudipta Roy1, Kartik Chandra Mondal, Lennard Krause

  • 1Institut für Anorganische Chemie, Georg-August-Universität , Tammannstraße 4, 37077 Göttingen, Germany.

Journal of the American Chemical Society
|November 11, 2014
PubMed
まとめ

カリウム金属は,シリコンを含むシリロン分子を活性化させ,C−H結合による選択反応を可能にします. これは,ラジカルアニオン中間体を通ってサイクリックシリレンを形成し,EPRスペクトロスコーピーで確認されます.

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