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Updated: Apr 20, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

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ボロン触媒によるキノリンのシライラティブ還元:選択的なsp3 C-Si結合形成

Narasimhulu Gandhamsetty1, Seewon Joung, Sung-Woo Park

  • 1Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS) , Daejeon 305-701, South Korea.

Journal of the American Chemical Society
|November 21, 2014
PubMed
まとめ

新しいシライラティブ還元法により,トリアリルボラン触媒を用いてキノリンは多用途のテトラヒドロキノリンに変換されます. この効率的な方法は,C ((sp ((3)) -Si結合を形成し,スケーラブルな合成のための優れたステレオ選択性を提供します.

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