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Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides
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Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides

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鉄複合体におけるN-N裂解に対するアルカリ金属制御

Katarzyna Grubel1, William W Brennessel, Brandon Q Mercado

  • 1Department of Chemistry, Yale University , New Haven, Connecticut 06511, United States.

Journal of the American Chemical Society
|November 21, 2014
PubMed
まとめ

この研究は,アルカリ金属のカチオンサイズが電力を減少させず,鉄 (Fe) 表面の窒素 (N2) アクティベーションを制御することを明らかにしています. N2三重結合を裂くには少なくとも3つのFe原子が必要です.

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