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Updated: Apr 20, 2026

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
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コバロキシームと水素の反応: 製品と熱力学

Deven P Estes1, David C Grills, Jack R Norton

  • 1Department of Chemistry, Columbia University , 3000 Broadway, New York, New York 10027, United States.

Journal of the American Chemical Society
|November 27, 2014
PubMed
まとめ

研究者らは,高圧水素下でのUV-VIS光譜を用いてコバルト水化物の中間物質を観察した. 彼らは新しいコバルト (I) 化合物を特徴付け,そのO-H結合解離の自由エネルギーとpK (a) を決定した.

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The addition of a hydrogen halide to 1,3-butadiene gives a mixture of 1,2- and 1,4-adducts. Since more substituted alkenes are more stable, the 1,4-adduct is expected to be the major product. However, the product distribution is strongly influenced by temperature; low temperature favors the 1,2-adduct, whereas the 1,4-adduct is predominant at high temperature.
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A significant aspect of hydroboration–oxidation is the regio- and stereochemical outcome of the reaction.
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