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Updated: Apr 19, 2026

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach
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Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach

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二重金属マクロサイクル内のAg-π相互作用によるディトピックアロマティックゲスト分子の多点認識

Kenichiro Omoto1, Shohei Tashiro, Masumi Kuritani

  • 1Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan.

Journal of the American Chemical Society
|December 6, 2014
PubMed
まとめ

研究者らは,銀 ((I) センターとアントラセンの壁を持つ新しいマクロサイクリックホストを開発しました. この宿主体は,銀-π相互作用によってフェロセンのような芳香分子に効果的に結合し,高い結合定数を持つ安定したインクルージョン複合体を形成します.

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The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
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Removing one hydrogen from the intervening CH2 group...
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