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ゲミナル・ビス (((ボロナート)) とビニルハリドのエナチオトーピックグループ選択的クロスカップリングによる非ラセミックアルリルボロナートとビニルハリド

Bowman Potter1, Adam A Szymaniak, Emma K Edelstein

  • 1Department of Chemistry, Merkert Chemistry Center, Boston College , Chestnut Hill, Massachusetts 02467, United States.

Journal of the American Chemical Society
|December 9, 2014
PubMed
まとめ

チラルパラジウム触媒は,ブロモアルケンとボロ酸塩の非対称なクロスカップリングを可能にし,エナチオセレクティブのアリルボロ酸塩を生成します. これらの中間物質は,価値のある二次または三次アルリルアルコールに変換することができます.

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