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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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perfluorinated aryl azidesの1,3-二極性サイクル添加反応は,エナミンとストレングディポラロフィールと結合している

Sheng Xie1, Steven A Lopez, Olof Ramström

  • 1Department of Chemistry, KTH-Royal Institute of Technology , Teknikringen 36, Stockholm, Sweden.

Journal of the American Chemical Society
|January 2, 2015
PubMed
まとめ

パルフッロアリルアジド (PFAA) は,フェニルアジドよりもエナミンのサイクル添加で著しく速く反応します. この反応性の向上は,PFAAによるものです.

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