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Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy
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C中心のルイス酸 (カルボカチオン) に向かって,ルイス基本性のスケール

Herbert Mayr1, Johannes Ammer, Mahiuddin Baidya

  • 1Department Chemie, Ludwig-Maximilians-Universität München , Butenandtstraße 5-13, Haus F, 81377 München, Germany.

Journal of the American Chemical Society
|January 3, 2015
PubMed
まとめ

この研究では,ベンジヒドリリウムイオンのルイス酸性と,様々な塩基のルイス塩基性を定量化し,反応性のスケールを確立しました. それは,反応性,ルイス酸性,および計算されたメチルアニオン相性との間の線形相関を明らかにし,速度-均衡関係のための境界を定義します.

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