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移行金属ヒドリドからのH•移転による酸素安定化ラジカルの直接生成

Jonathan L Kuo1, John Hartung, Arthur Han

  • 1Department of Chemistry, Columbia University , 3000 Broadway, New York, New York 10027, United States.

Journal of the American Chemical Society
|January 9, 2015
PubMed
まとめ

移行金属ヒドリドは,エノールエーテルへのH•移転経由でα-アルコキシラジカルを効率的に生成します. これらのラジカルは,ダイアステロセレクティブ5エクソサイクリングを可能にし,代用されたテトラヒドロフーランへの直接的な経路を提供します.

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