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Updated: Apr 17, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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オキシアイロン (IV) ポルフィリンにおけるフェリルプロトネーションと,酸素伝達におけるフェリルの役割

Nicholas C Boaz1, Seth R Bell, John T Groves

  • 1Department of Chemistry, Princeton University , Princeton, New Jersey 08544, United States.

Journal of the American Chemical Society
|February 5, 2015
PubMed
まとめ

フェリル・ポルフィリンは溶液でプロトン化され,ビス・アクア・アイアン (III) ポルフィリン・カチオン・ラジカルを形成する. この新しい均衡は,独特の陽子結合の水素原子移転機構を通じて,炭化水素酸化に影響を与えます.

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Oxidation of Phenols to Quinones

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