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Updated: Apr 17, 2026

Monitoring Equilibrium Changes in RNA Structure by 'Peroxidative' and 'Oxidative' Hydroxyl Radical Footprinting
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炭素ラジカル 炭素ラジカル 水素プロキシアルキル基 (QOOH) の直接観察と運動学

John D Savee1, Ewa Papajak1, Brandon Rotavera1

  • 1Combustion Research Facility, Mail Stop 9055, Sandia National Laboratories, Livermore, CA 94551-0969, USA.

Science (New York, N.Y.)
|February 7, 2015
PubMed
まとめ

研究者は,酸化反応における重要な中間物質である水素プロキシアルキル基 (QOOH) を直接観察した. 共振安定化は,QOOHの反応性に大きな影響を及ぼし,不飽和有機酸化における中介物質の寿命が長くなります.

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