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Updated: Apr 17, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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核愛性の分子間化学とジメチルカルベンの反応性

Hui Cang1, Robert A Moss, Karsten Krogh-Jespersen

  • 1Department of Chemistry & Chemical Biology, Rutgers, The State University of New Jersey , New Brunswick, New Jersey 08903, United States.

Journal of the American Chemical Society
|February 11, 2015
PubMed
まとめ

ディメチルカルベン (DMC) は,添加反応において,非常に反応性の高い核性カルベンとして作用する. 実験的および計算的研究により,アルケーンとの反応において,その負の活性化エネルギーとエンタルピーが確認されています.

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