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Updated: Apr 17, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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O2によるCp*Ir (III) (NHC) (Me) (Cl) による酸化機能化:希少なバイメタリックIr (IV) μ-オクソ中間物質の特定

Matthew C Lehman1, Dale R Pahls2, Joseph M Meredith3

  • 1‡Department of Chemistry, North Carolina State University, 2620 Yarbrough Drive, Raleigh, North Carolina 27695-8204, United States.

Journal of the American Chemical Society
|February 22, 2015
PubMed
まとめ

この研究は,空気を酸化剤として使用したイリジウム複合体からメタノールの形成を詳細に説明しています. 重要な中間物質である,Ir (IV) -O-Ir (IV) コアを持つダイアリジウムバイメタリック複合体を分離し,特徴づけました.

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