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Updated: Apr 16, 2026

Engineering Molecular Recognition with Bio-mimetic Polymers on Single Walled Carbon Nanotubes
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Engineering Molecular Recognition with Bio-mimetic Polymers on Single Walled Carbon Nanotubes

Published on: January 10, 2017

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光センサーの合理的な設計により,エナティオメア組成とキラル機能性アミンの濃度の両方を同時に決定できます

Kaili Wen1, Shanshan Yu1, Zeng Huang1

  • 1†Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, China 610064.

Journal of the American Chemical Society
|March 20, 2015
PubMed
まとめ

新しい光センサーが,キラルアミン濃度とエナティオメア成分を同時に測定しています. この二重応答センサーは,多様なキラル基板を分析するための敏感で選択的な方法を提供します.

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Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
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The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...
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