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Updated: Apr 16, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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無機エナミンの効果による急速な"ウィティグのような"反応

Stella A Gonsales1, Matias E Pascualini1, Ion Ghiviriga1

  • 1Department of Chemistry, Center for Catalysis, University of Florida, P.O. Box 117200, Gainesville, Florida 32611, United States.

Journal of the American Chemical Society
|March 21, 2015
PubMed
まとめ

トライアニオニックピンサーリガンドを併用した新型のボルンガムアルキリジネ複合体は,無機エナミン効果に起因する高速なウィティグのような反応において,核愛性が強化されたことを示している. この反応性は,効率的な酸素原子をカルボニル基板に転送することを可能にします.

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