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Updated: Apr 15, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

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ポルフィリン-Co (III) "窒素基"の特徴 触媒性窒素移転反応に関連する種

Monalisa Goswami, Volodymyr Lyaskovskyy, Sérgio R Domingos

  • 1§Lehrstuhl für Bioanorganische Chemie, Department Chemie und Pharmazie, Universität Erlangen-Nürnberg. Egerlandstraße 1, D-91058 Erlangen, Germany.

Journal of the American Chemical Society
|April 7, 2015
PubMed
まとめ

この研究は,コバルト触媒反応におけるコバルト・ナイトレン・ラジカル中間物質の特徴を示しています. 研究者らは,モノ・ビス・ナイトレンの種を特定し,ナイトレンの移転と触媒性アジリディネーションにおける重要な役割を明らかにした.

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Radicals adjacent to electron-donating groups are called nucleophilic radicals. These radicals readily react with electrophilic alkenes. The SOMO–LUMO interactions are the driving force for the reaction, where the high-energy SOMO of the electron-rich, nucleophilic radicals interacts with the low-energy LUMO of the electron-deficient, electrophilic alkenes. Such SOMO–LUMO interactions are the basis of reactive radical traps, affecting the selectivity in radical reactions. For...
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