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Updated: Apr 15, 2026

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
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ナフトールの非対称的脱オマティゼーションは,Rh触媒C ((sp2) -H機能化/無効化反応を介して行われる

Jun Zheng1, Shao-Bo Wang1, Chao Zheng1

  • 1State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.

Journal of the American Chemical Society
|April 9, 2015
PubMed
まとめ

新しいRh触媒反応により,ナフトールとアルキンからキラル型スピロサイクリックエノンが生成されます. このC-H機能化の方法により,四次元の立体性中心を持つ高度にエナチオ濃縮された化合物が得られます.

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