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Updated: Apr 13, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
10:12

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

Published on: April 4, 2014

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メタラサイクル媒介のクロスカップリングによる高機能デカリンの合成

Haruki Mizoguchi1, Glenn C Micalizio1

  • 1Department of Chemistry, Burke Laboratory, Dartmouth College, Hanover, New Hampshire 03755, United States.

Journal of the American Chemical Society
|May 2, 2015
PubMed
まとめ

この研究では,天然製品や医薬品における重要な構造である角置換デカリンを合成するための新しい金属サイクル媒介無効反応を導入しています. この反応は,中間の安定性を制御し,新しいステレオセンターを持つ多様なポリサイクル化合物を生成します.

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