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Updated: Apr 12, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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電子の移転は,2- (((BMes2) ピレンと2,7- (((BMes2) ピレンの還元形態に

Lei Ji1, Robert M Edkins1, Andreas Lorbach1

  • 1†Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.

Journal of the American Chemical Society
|May 8, 2015
PubMed
まとめ

ボロンを含むピレン化合物の減少は,ピレン核とボロン原子の間で電子を異動させるアニオンを生成する. これらの研究は,結果として発生した基幹アニオンとシングレットダイアニオンに独特の半キノイドおよびキノイド構造を明らかにしています.

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