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Updated: Apr 12, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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(2 + 2) ベンジンをエンドヘドラル金属フルフルレンにサイクル添加するM3N@C80 (M = Sc, Y):旋回中介機構

Tao Yang1, Shigeru Nagase2, Takeshi Akasaka3

  • 1‡Institute for Molecular Science, Okazaki 444-8585, Japan.

Journal of the American Chemical Society
|May 15, 2015
PubMed
まとめ

密度関数計算により,メタルフルレンへのベンジンサイクロアディションは,ダイラジカルメカニズムに従っていることが明らかになった. エンドオヘドラルクラスターは,Sc3N@C80が閉じたケージアダクトを好み,Y3N@C80が開いたケージ構造を生むことで,地域選択性とケージ構造に影響を与えます.

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