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Updated: Apr 11, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI

Published on: November 22, 2016

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三角形 π ラジカルアニオンによって形成された K4 構造の発見

Asato Mizuno, Yoshiaki Shuku, Rie Suizu1

  • 1∥Department of Nanomaterials Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan.

Journal of the American Chemical Society
|June 11, 2015
PubMed
まとめ

研究者らは,ナフタレン二酸化物 (NDI) -Δ基アニオンを電気化学的に結晶化することで,難解なK4炭素構造を合成した. この発見は,新しい炭素アロトロプとそのユニークな電子特性を探求するための新しい道を開きます.

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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates06:35

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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes10:51

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This lesson delves into the geometry of a radical, which is influenced by the electronic structure of the molecule. The principle is similar to that of a lone pair, where the unpaired electron influences the geometry at the radical center.
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