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Updated: Apr 10, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Published on: November 21, 2017

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アリルエレクトロフィールによるNi (II) からNi (IV) への酸化により,Ni-メディエーションによるアリル-CF3 カップリングが可能になる

James R Bour1, Nicole M Camasso1, Melanie S Sanford1

  • 1University of Michigan, Department of Chemistry, 930 North University Avenue, Ann Arbor, Michigan 48109, United States.

Journal of the American Chemical Society
|June 17, 2015
PubMed
まとめ

この研究は,ニッケル (IV) 複合体の生成と反応を詳細に説明し,それらは容易に形成され,重要な結合形成段階を経ることを示しています. これらの発見は,ニッケル (IV) が触媒結合反応において重要な役割を果たす可能性があることを示唆している.

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