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Updated: Apr 9, 2026

Light-driven Enzymatic Decarboxylation
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新しいコファクターは,1,3-二極サイクロアディションによるα,β不飽和酸デカルボキシル化をサポートする

Karl A P Payne1, Mark D White1, Karl Fisher1

  • 1Centre for Synthetic Biology of Fine and Speciality Chemicals, Manchester Institute of Biotechnology, University of Manchester, 131 Princess Street, Manchester M1 7DN, UK.

Nature
|June 18, 2015
PubMed
まとめ

菌類のFdc1酵素は,新しいプレニル化フラビン共因子を用いて,可逆性芳香性デカルボキシル化を触媒化する. この反応メカニズムは,独特の酵素的1,3-二極サイクロアディションを含み,化学合成のための新しい経路を提供します.

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